Metal hydride-based composite materials with improved thermal conductivity and dimensional stability properties


ISSN 1121-7588
Marzia Pentimalli1, Andrea Frazzica2, Angelo Freni2, Enrico Imperi3, Franco Padella1
1ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria diGaleria, Rome, Italy
2CNR, National ResearchCouncil, ITAE, Istituto di Tecnologie Avanzate per l'Energia "Nicola Giordano”, Salita Santa Lucia Sopra Contesse 5, 98126, Messina, Italy
3Labor s.r.l., via Giacomo Peroni 386, 00131 Rome, Italy

Abstract

To address the issues of poor thermal conductivity and fragmentation of metal hydride particles undergoing hydriding/dehydriding reactions, a metal hydride-based composite material was developed. The active metal phase was embedded in a silica matrix and agraphite filler was incorporated by ball milling. A set of compact pellet samples at different composition were prepared and tested. Experimental data obtained from the thermal conductivity measurements shown that using powder graphite produced a quite linear increase in the thermal conductivity of the metal hydride –silica composite. Ongoing studies include composition optimization as well as longterm testing upon cycling of such metal hydride composites to evaluate their potentiality in technological hydrogen storage applications.
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