Water gas shift reaction in Pd-based Membrane Reactors


ISSN 1121-7588
A. Basile1, P. Pinacci2, S. Tosti3, M. De Falco4, C. Evangelisti5, T. Longo1, S. Liguori1, A. Iulianelli1
1Institute on Membrane Technology of National Research Council (ITM-CNR), Via P. Bucci Cubo 17/C c/o University of Calabria, Rende (CS) – 87036 – Italy
2Erse S.p.A., via Ribattino 54, 20134 Milano, Italy
3ENEA, Unità Tecnico Scientifica Fusione, C.R. ENEA Frascati, via E. Fermi 45, Frascati, 00044 Roma, Italy
4Department of Chemical Engineering, University of Rome ‘‘La Sapienza’’, via Eudossiana, 18, 00184 Rome, Italy
5Department of Chemistry and Industrial Chemistry, University of Pisa, via Risorgimento 35, 56126 Pisa, Italy

Abstract

Water-gas shift reaction is an important industrial reaction, used for producing synthesis gas and ammonia as well as pure hydrogen for supplying at PEM fuel cells. In this work, an overview on water gas shift reaction performed in Pd-based membrane reactors is shown, paying particular attention to the influence on the performances of some operating variables such as reaction temperature, reaction pressure, H2O/CO molar ratio and sweep gas.
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