Aluminum Oxide ceramics obtained by commercial starch consolidation with gradient porosity


ISSN 1121-7588
Rogério Pinto Mota1, Rodrigo Sampaio Fernandes2, Elson de Campos3, Emerson Ferreira de Lucena3, Mauricio A Algatti1
1FEG-DFQ-UNESP, Campus de Guaratinguetá, Av. Ariberto Pereira da Cunha 333, 12516-410, Guaratinguetá, SP,Brazil
2Universidade Federal de Alfenas, Departamento de Ciências e Tecnologia, Campus de Poços de Caldas, MG, Brazil
3Escola de Especialistas da Aeronáutica, Av. Brig. Adhemar Lyrio, s/n, 12.500-000 Guaratinguetá, SP, Brazil

Abstract

The starch consolidation technique is commonly used for obtaining porous ceramics due to bonding and porous-maker starch characteristic during gelling process. The method adopted here improved the water drainage by using a plaster porous base (70 and 90 consistency values) improving the water drainage by action of gravity and the capillary effect. It used slip with 50 vol% solids and as precursors oxide A-1000SG and commercial cornstarch with a mass concentration varying from 10 to 40%. For comparison between the present method and the common one, slip was put in impermeable and permeable base moulds. The gelling occurred at 70ºC for 2 hours and the drying at 110ºC. Pre-sintering was carried out at 1000ºC and the sintering at 1600ºC with a plateau of 1 hour. Results showed that the plaster consistency of the mould bases was preponderant on ceramics porosity. Porosity and apparent density measurements using light and electron microscopy revealed variation of 5% of porosity from the top to the bottom of the samples.
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